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    Higher-order glass-transition singularities in colloidal systems with attractive interactions

    K. Dawson1, G. Foffi1, M. Fuchs2, W. Götze2, F. Sciortino3, M. Sperl2, P. Tartaglia3, Th. Voigtmann2, and E. Zaccarelli1

    • 1Irish Centre for Colloid Science and Biomaterials, University College Dublin, Belfield, Dublin 4, Ireland
    • 2Physik-Department, Technische Universität München, D-85747 Garching, Germany
    • 3Dipartimento di Fisica and Istituto Nazionale per la Fisica della Materia, Università di Roma La Sapienza, Piazzale Aldo Moro 2, I-00185 Roma, Italy

    Phys. Rev. E 63, 011401 – Published 19 December, 2000

    DOI: https://doi.org/10.1103/PhysRevE.63.011401

    Abstract

    The transition from a liquid to a glass in colloidal suspensions of particles interacting through a hard core plus an attractive square-well potential is studied within the mode-coupling-theory framework. When the width of the attractive potential is much shorter than the hard-core diameter, a reentrant behavior of the liquid-glass line and a glass-glass-transition line are found in the temperature-density plane of the model. For small well-width values, the glass-glass-transition line terminates in a third-order bifurcation point, i.e., in a A3 (cusp) singularity. On increasing the square-well width, the glass-glass line disappears, giving rise to a fourth-order A4 (swallow-tail) singularity at a critical well width. Close to the A3 and A4 singularities the decay of the density correlators shows stretching of huge dynamical windows, in particular logarithmic time dependence.

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